An ideal gas is in thermodynamic equilibrium. The number of degrees of freedom of a molecule of the gas is š‘›. The internal energy of one mole of the gas is š‘ˆš‘› and the speed of sound in the gas is vš‘›. At a fixed temperature and pressure, which of the following is the correct option? (A) v3 < v6 and š‘ˆ3 > š‘ˆ6 (B) v5 > v3 and š‘ˆ3 > š‘ˆ5 (C) v5 > v7 and š‘ˆ5 < š‘ˆ7 (D) v6 < v7 and š‘ˆ6 < š‘ˆ7

To determine the correct option, we need to analyze the relationship between the degrees of freedom n, the internal energy Un, and the speed of sound vn in an ideal gas.

1. Internal Energy Un:

For an ideal gas, the internal energy Un is given by:

Un=n2RT

where:

  • n is the number of degrees of freedom,

  • R is the universal gas constant,

  • T is the temperature.

From this equation, it is clear that internal energy increases with the number of degrees of freedom n. Therefore:

U3<U5<U6<U7

2. Speed of Sound vn:

The speed of sound vn in an ideal gas is given by:

vn=γRTM

where:

  • γ=CpCv=1+2n is the adiabatic index,

  • R is the universal gas constant,

  • T is the temperature,

  • M is the molar mass of the gas.

The adiabatic index Ī³ decreases as the number of degrees of freedom n increases. Specifically:

γ=1+2n

Thus, as n increases, Ī³ decreases, and the speed of sound vn decreases. Therefore:

v3>v5>v6>v7

3. Analyzing the Options:

  • Option (A): v3<v6 and U3>U6.
    This is incorrect because v3>v6 and U3<U6.

  • Option (B): v5>v3 and U3>U5.
    This is incorrect because v5<v3 and U3<U5.

  • Option (C): v5>v7 and U5<U7.
    This is correct because v5>v7 and U5<U7.

  • Option (D): v6<v7 and U6<U7.
    This is incorrect because v6>v7 and U6<U7.

Final Answer:

C

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